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Advanced Inorganic Chemistry

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Title: Advanced Inorganic Chemistry


1
Advanced Inorganic Chemistry
  • Chem 342
  • Miessler Tarr, 4th edition

2
Syllabus
  • Goals Objectives
  • Textbook (bring to class)
  • Attendance Grading2 take-home exams final
    (55)homework (15)literature presentation
    (10)literature exam (15)participation (5)

3
Course Content
  • Chapters 1-5 (bonding theories)Chapter 6,
    Acid-Base Donor-Acceptor TheoryChapters 9, 10,
    12 (coordination chemistry)
  • Chapter 11, Coord Chem Electronic Spectra
    Chapters 13, 14 (organometallic
    chemistry)Chapter 16, Bioinorganic
    Environmental Chem
  • Experimental Methods in Inorganic Chemistry
  • Nanochemistry noncovalent interactions

4
Chapter 1 - Intro to Inorganic
  • What is it?
  • Sub-fieldsmain-group, coordination chemistry,
    organometallic, bioinorganic, physical inorganic,
    heavy-metals, trans-uranium..
  • How does it compare to Organic Chemistry?
  • Compounds with single, double, triple bonds
  • Inorganic compounds can contain quadruple bonds
    (sigma pi pi delta bond)Cl4ReReCl42
  • Carbon maximum number of connections 4
  • Inorganic carbon is found in carbon cluster
    compounds, in bridging alkyl groups

5
Chapter 1 - Intro to Inorganic
  • Organic H is a terminal atom, only bonds to one
    other element. Inorganic The same rules do not
    apply. Lewis structure of B2H6?
  • Organic Limited geometries (linear, trigonal
    planar, tetrahedral, bent). Inorganic Also
    square planar, trigonal bipyramid, octahedral,
    and more
  • Inorganic also has aromatic compounds (borazine
    B3N3H6)

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11
History of Inorganic Chemistry
  • Ancient times through Alchemy
  • Descriptive chemistry, techniques, minerals (Cu
    compounds), glasses, glazes, gunpowder
  • 17th Century
  • Mineral acids (HCl, HNO3, H2SO4), salts and their
    reactions, acid and bases
  • Quantitative work became important, molar mass,
    gases, volumes
  • 1869 The periodic table
  • Late 1800s Chemical Industry
  • Isolate, refine, purify metals and compounds
  • 1896 Discovery of Radioactivity
  • Atomic structure, quantum mechanics, nuclear
    chemistry (through early 20th century)

12
History of Inorganic Chemistry
  • 20th Century
  • Coordination chemistry, organometallic chemistry
  • WWII Military projects Manhattan project, jet
    fuels (boron compounds)
  • 1950s
  • Crystal field theory, ligand field theory,
    molecular orbital theory
  • 1955
  • Organometallic catalysis of organic reaction
    (polymerization of ethylene)
  • Modern Issues
  • Bioinorganic chemistry (nitrogen fixation),
    modeling biochemical process, enzymes, x-ray
    crystallography,
  • nanochemistry, manipulation of noncovalent
    interactions

13
Take a Look
  • Literature taken from Inorganic Chemistry
  • Take a quick lookWhat are the sub-fields?What
    do you recognize, understand?What looks foreign?
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