Title: Iron-Pnictide Superconductors as Multiband Correlated (Semi)Metals
1Iron-Pnictide Superconductors as Multiband
Correlated (Semi)Metals
Zlatko Tesanovic, Johns Hopkins
University E-mail zbt_at_pha.jhu.edu
Web http//www.pha.jhu.edu/zbt
T. Y. Chen et al., Nature 453, 1224 (2008) V.
Cvetkovic and ZT, EPL 85, 37002 (2009)
arXiv/0804.4678 V. Cvetkovic and ZT,
arXiv/0808.3742
- Iron Pnictides Semimetals turned
Superconductors - Superconducting Gap in FeAs (PCAR, ARPES, ¹w,
STM) - Minimal Model of FeAs planes Different from
CuO2!! - Multiband Magnetism and Superconductivity in FeAs
2Pnictides (Greek for chocking)Semiconductors ?
Semimetals ? Superconductors
3Fe-pnictides Semimetals ? Superconductors
4Fe-pnictides Semimetals ? Superconductors
5Tc (K)
2008
courtesy of J. Hoffman
6Superconductivity in Fe
K. Shimizu et al. Nature 412, 316-318 (2001).
7Cu-oxides versus Fe-pnictides
However, there are also many differences! This
may add up to new and interesting physics
8Key Difference 9 versus 6 d-electrons
- In CuO2 a single hole in a filled 3d orbital
shell - A suitable single band model should work
- In FeAs large and even number of d-holes
- A multiband model is likely necessary
9Fe-pnictides Semimetals ? Superconductors
- In contrast to CuO2, all d-bands in FeAs are
either nearly empty (electrons) or nearly full
(holes) and far - from being half-filled.
- FeAs are less correlated than CuO2
10Phase diagram of Fe-pnictides
Like CuO2, phase diagram of FeAs has SDW (AF) in
proximity to the SC state.
11ARPES
ARPES and dHvA see coherent (metallic) bands in
reasonable agreement with LDA.
12Minimal Model of FeAs layers I
V. Cvetkovic and ZT, EPL 85, 37002 (2009)
arXiv/0804.4678
- Puckering of FeAs planes is essential
- All d-orbitals are near EF
- Large overlap with As p-orbitals below EF ?
enhanced itinerancy of d electrons - defeats Hunds rule and large local moment
13Minimal Model of FeAs layers II
V. Cvetkovic and ZT, EPL 85, 37002 (2009)
arXiv/0804.4678
We consider an effective 2D model with 5 Fe 3
As orbitals
Two orbital model (S. Raghu, et al, PRB 77,
220503R (2008)) reconstructs the FS shape but not
its orbital content
dxz
dyz
dxy
dxx-yy
d2zz-xx-yy
odd parity
even parity
The importance of Fe 3d As 4p
hybridization Without pnictide atoms many
hopping processes would vanish by symmetry.
14Hunds Rule Defeated
V. Cvetkovic and ZT, EPL 85, 37002 (2009)
arXiv/0804.4678
Hunds rule rules for Mn2 all five
d-electrons line up to minimize Coulomb
repulsion ? S 5/2
- Puckering of FeAs planes is essential
- All d-orbitals are near EF
- Large overlap with As p-orbitals below EF ?
enhanced itinerancy of d electrons - defeats Hunds rule and large local moment
Haule, Shim and Kotliar, PRL 100, 226402 (2008)
15Minimal Model of FeAs layers III
V. Cvetkovic and ZT, EPL 85, 37002 (2009)
arXiv/0804.4678
Important Near EF e and h bands contain
significant admixture of all five Wannier
d-orbitals, dxz and dyz of odd parity (in FeAs
plane) and the remaining three d-orbitals of even
parity in FeAs plane ?
16Nesting and Valley Density-Wave (VDW) in
Fe-pnictides I
V. Cvetkovic and ZT, EPL 85, 37002 (2009)
arXiv/0804.4678
V. Cvetkovic and ZT, arXiv/0808.3742
Turning on moderate interactions ?
VDW itinerant multiband CDW (structural), SDW
(AF) and orbital orders at q M
ed
d
m
c
ec
SDW, CDW, ODW or combinations thereof ? VDW
Semiconductor
Semimetal
17Nesting and Valley Density-Wave (VDW) in
Fe-pnictides II
V. Cvetkovic and ZT, EPL 85, 37002 (2009)
arXiv/0804.4678
V. Cvetkovic and ZT, arXiv/0808.3742
d
c
18Fictitious Superconductor ? VDW in
Fe-pnictides
V. Cvetkovic and ZT, EPL 85, 37002 (2009)
arXiv/0804.4678
V. Cvetkovic and ZT, arXiv/0808.3742
(. . .)
19 The Coastline of the Fermi Sea
?
New REOFeAs SC Tc ? 55K
20What can ? tell us about superconducting state ?
Standard BCS theory works well in materials like
Nb, Sn or Hg. In Pb and more complex systems
(V3Sn) one needs strong coupling theory (2?/Tc
? 4-6 )
21What can ? tell us about superconducting state ?
Our results for FeAs appear inconsistent with
these features
22 ? in FeAs superconductors I
T. Y. Chen et al., Nature 453, 1224 (2008)
BTK analysis ? 2D 13.34 0.3 meV TC 42 K
Conclusions Point-contact Andreev reflection
spectroscopy indicates a nodeless superconducting
gap and no SC pseudogap behavior. Very different
from high Tc cuprate superconductors !!
23 ? in FeAs superconductors II
V. Cvetkovic and ZT, EPL 85, 37002 (2009)
arXiv/0804.4678
Conclusions Conventional phonon-mechanism is
unlikely but so is Mott limit-induced repulsion
of the cuprate d-wave kind. We have something new
!!
24Emerging consensus (PCAR, ARPES, STM, mW,
)nodeless single in 1111, two s in
122, nodes ??
NMR sees nodal behavior ( T2 ) in 1111
Multiband superconductivity in Fe-pnictides !?
25Josephson Effect Between FeAs and Pb
X. Zhang et al., PRL 102, 147002 (2009)
Point Contact Junction
- I-V characteristics are resistively like a
shunted junction - Shapiro steps were observed under microwave
irradiation
Strong indication of s-wave like SC state
courtesy of R. Greene
Ba1-xKxFe2As2/Pb
26Minimal Model of FeAs Layers III
V. Cvetkovic and ZT, EPL 85, 37002 (2009)
arXiv/0804.4678
FeAs are different from CuO2 Charge
carriers are more itinerant and less localized on
atomic sites. Multiband description is necessary,
unlike an effective single band model of cuprates
27Interactions in FeAs I
V. Cvetkovic and ZT, EPL 85, 37002 (2009)
arXiv/0804.4678
28Interactions in FeAs II
V. Cvetkovic and ZT, EPL 85, 37002 (2009)
arXiv/0804.4678
V. Cvetkovic and ZT, arXiv/0808.3742
e-h
Typically, we find Ws is dominant ? Valley
density-wave(s) (VDW) in FeAs
29Valley Density-Wave (VDW) and SC in FeAs I
V. Cvetkovic and ZT, arXiv/0808.3742
V. Stanev, J. Kang, ZT, PRB 78, 184509 (2008)
Outcome combined SDW/CDW/ODW and structural
orders at q M ? VDW
Josephson terms in k-space (ccdd) play key
role in SC
30Valley Density-Wave (VDW) and SC in FeAs II
The condition for interband SC is actually
milder
but
RG calculations indicate, near a VDW state
A. V. Chubukov et al, PRB 78, 134512 (2008)
In Fe-pnictides interband superconductivity (s
or s- state) is a strong possibility (perhaps
with little help from phonons)
M. Parish, J. Hu, and B. A. Bernevig, PRB 78,
144514 (2008)
31Two Kinds of Interband Superconductivity
d
V. Stanev, J. Kang, ZT, PRB 78, 184509 (2008)
Interband pairing acts like Josephson coupling in
k-space. If G2 is repulsive ? antibound Cooper
pairs (sSC)
c
Type-II (intrinsic) interband SC
Type-I interband SC
32Unified Model of Valley Density-Wave (VDW) in
FeAs
V. Cvetkovic and ZT, arXiv/0808.3742
also, SO(6) Podolsky, Kee, Kim, arXiv/0812.2907
VDW in Fe-pnictides is a (nearly) highly
symmetric combination SDW/CDW/ODW
33Interplay of VDW and SC in FeAs I
This is true interband SC since U gt 0
different from U lt 0
34Interplay of VDW and SC in FeAs II
V. Cvetkovic and ZT, arXiv/0808.3742
Also, A. V. Chubukov et al, PRB 78, 134512 (2008)
35Conclusions
- Iron pnictides are semimetals turned
superconductors - Correlations are significant, hence a SDW in
parent compounds, but weaker than in cuprates - Superconducting gap has substantial s-wave
character - Both magnetism and superconductivity are
intrinsically multiband in nature s interband
SC is a likely possibility near a nesting-driven
SDW
Zlatko Tesanovic, Johns Hopkins
University E-mail zbt_at_pha.jhu.edu
Web http//www.pha.jhu.edu/zbt