Hazardous Materials Transportation

1

• Hazardous Materials Transportation
• March 12, 2008

2
Truck Bombs Used

• 1983, U.S. Embassies, Lebanon Kuwait
• 1983, U.S. Marine Barracks, Lebanon
• 1988, USO Club, Italy
• 1992 and 1993, U.S. Embassy, Peru
• 1993, World Trade Center, New York
• 1995, Federal Building, Oklahoma City
• 1998, U.S. Embassies, Kenya, Tanzania

3
Algerian charged with transporting explosives

• December 17, 2000
• Man charged with transporting explosives
• 32 year old Algerian tried to smuggle 100 pounds
  of explosive material and timer across border at
  Port Angeles, Wa.
• Planned to use at LAX on New Years Eve Seattles
  Space Needle was secondary target

4
Written Security Plan (Part 172.800 - .804)

• Part 107.601, those who offer or transport
• RC quantity of class 7
• gt55 lb. Class 1.1, 1.2, 1.3
• gt1.06 qt. Poison inhalazion hazard Zone A
• Bulk shipment of HM in package greater than 3500
  gallons (liquid, gas) or 468 cubic ft solid
• Placarded loads
• Agent or toxin regulated by CDC

5
Components of Written Plan (Part 172.802)

• Assess transportation security risks and measures
  to address the risks
• Personnel security
• Unauthorized access
• En route security
• Plan must be
• In writing
• Available to employees
• Changed as conditions change

6
Profile of Terrorist Act

• Target select and rate value (how much damage,
  how many dead, media coverage)
• Casing observe operations, schedules, etc. and
  prepare written plan
• Surveillance physical plant equipment written
  security plan web site
• Rehearsal limited resources cant be wasted

7
Driver Security

• Be alert when leaving criminal surveillance
  starts within a mile of your origin
• Do not discuss your cargo, destination or trip
  near people you dont know
• Do not park under bridges, overpasses
• Survey surroundings before leaving truck
• Make sure radio or cell phone is working properly
• Perform quick walkaround at every stop
• If in doubt, call 911

8
Driver Security (cont.)

• Avoid being boxed in leave room in front and at
  rear
• Keep truck locked at all times
• Watch for people following you
• Team driving? Leave one person in the truck
• Padlock cargo doors use 5th wheel lock
• When in doubt, call 911

9
Hazardous Materials Regulations (HMR)

• Regulated by US DOT
• 49 CFR 100-180
• Enforced by Pipeline and Hazardous Materials
  Safety Administration (PHMSA)
• Regulations apply to
• Shippers, handlers, transporters, packaging
  manufacturers, testers, etc.
• All modes (highway, air, rail, water)
• Domestic transportation of hazmat

10
Registration Part 107 Subpart G

• Applicability
• Exceptions
• General requirements
• Fees
• Recordkeeping

11
Training 172.700

• Applies to all hazmat employees
• Trained before they perform hazmat function and
  must be tested
• Training shall include
• General awareness
• Function-specific
• Safety self-protection/emergency response
• Security
• Modal-specific (highway, rail, air, etc.)
• Recurrent training every three (3) years
• Recordkeeping required

12
Record of Training172.704(d)

• Record must include
• Hazmat employees name
• Most recent completion date
• Description, copy or location of training
  materials
• Name and address of trainer
• Certification of training andtesting

13

General Requirements 171.2
Responsibility No person shall offer or accept
a hazardous material for transportation in
commerce ...unless its legal!
14
HMR per 49 CFR

• Part 107 Program Procedures
• Part 171 General Information, Definitions
• Part 172 Hazmat Table, Appendices A B,
  Markings, Labels, Shipping Papers, Placards,
  Training, Emergency Information, and Security
• Part 173 Shippers Requirements
• Part 177 Carriage by Public Highway
• Part 178 Specifications for Packages
• Part 180 Cargo Tank Inspections

15
Definitions Abbreviations171.8

• Hazardous Material
• Hazard Class
• Packing Group
• Bulk and Non-bulk
• Performance-oriented Packaging (POP)
• Combination Packaging

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Definitions Abbreviations171.8

• Limited Quantity
• Consumer Commodity
• Hazardous Substance
• Marine Pollutant
• Hazmat Employee
• Person

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Bulk Package

• Liquids - Maximum capacity over 119 gallons
• Solids - Maximum net capacity over 882 pounds and
  maximum capacity over 119 gallons
• Gases - Water weight capacity over 1,000 pounds

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IBC (Tote)
19
Composite IBCs
20
Flexible IBC
21
Cargo Tank
22
Tank Car
23
Steel Drum (Pail)
24
Plastic Jerrican (Pail)
25
Plastic Drum
26
Steel Drum
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Hazard Classes Divisions

• CLASS 1
• EXPLOSIVES
• 1.1, 1.2, 1.3, 1.4, 1.5, 1.6
• CLASS 2
• GASES
• 2.1 (FLAMMABLE)
• 2.2 (NONFLAMMABLE)
• 2.3 (POISON)
• CLASS 3
• FLAMMABLE LIQUID
• CLASS 4
• FLAMMABLE SOLIDS
• 4.1 (FLAMMABLE SOLIDS)
• 4.2 (SPONTANEOUSLY
• COMBUSTIBLE)
• 4.3 (DANGEROUS WHEN

• CLASS 5
• OXIDIZING SUBSTANCES
• 5.1 (OXIDIZER)
• 5.2 (ORGANIC PEROXIDES)
• CLASS 6
• POISONS
• 6.1 (POISON)
• 6.2 (INFECTIOUS)
• CLASS 7
• RADIOACTIVE
• CLASS 8
• CORROSIVES
• CLASS 9
• MISCELLANEOUS

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Combination Package
29
Consumer Commodity
30
DOT Hazmat Definition 49 CFR

• A substance or material that is capable of posing
  an
• unreasonable risk when transported in commerce.
• This term includes
• Substances (RQ)
• Wastes
• Marine pollutants
• Elevated temperature

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Packing Groups (PG)

• PG I - Great danger
• PG II Medium danger
• PG III Minor danger

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Hazardous MaterialsShipping Procedure

• Classify material
• Select packaging
• Communicate hazard
• Shipping papers
• Markings/labels
• Placards
• Provide emergency response information and phone
  number
• Load and segregate on vehicle

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Determining Hazard Classification

• Definition starts in Part 171.8 then follow
  instructions
• Origin of information Material Safety Data
  Sheet (MSDS)

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Performance-oriented Packaging (POP)

• UN Marking

35
(No Transcript)
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POP Packaging Marking (Combination Packaging)
PG Performance Level
Gross Weight
Packaging Identification Code
Solids/Inner Packaging
u n
4G/Y15/S/97 USA/AJO
United Nations Symbol
Year of Manufacture
Country of Authorization
Manufacturer ID
37
General Packaging Requirements 173.24

• Bulk and non-bulk
• New and reconditioned
• Specification andnon-specification packaging
• Must survive the transportation
• Must NOT leak
• Withstand impact
• No release of gases

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Additional Requirements 173.24(a)

• Inner closures upright
• Reduce friction
• Secure andcushioning
• No nails, staplesprotruding interior
• Withstand vibration

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HMT

• HAZMAT
• TABLE
• Appendix A
  Appendix B
• Appendix A-EPA Hazardous Substances
• Technical and chemical names
• RQ per package see definitions for mixtures
  solutions

• Appendix B-Marine Pollutants
• Technical and chemical names
• PP for severe marine pollutant
• gt 1 for SMP, 10 for other than SMP

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Hazardous Substance

• Listed on Appendix A
• Is in a quantity in one (1) package equal to or
  more than the RQ
• When in a mixture
• Equals or exceeds the concentrations
  corresponding to the materials RQ as shown in
  PPM table(i.e., 1 RQ 20 ppm)

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Hazardous SubstancesAppendix A to 172.101Table
1 Hazardous Substances other than Radionuclides
Reportable Quantity (RQ) Pounds (Kilograms)
Hazardous Substances
100 (45.4) 5000 (2270) 5000 (2270) 1 (0.454) 100
(45.4) 100 (45.4)
Acenaphthene Acetic Acid Acetone Aldrin Cupric
tartrate D001
5000 (2270)
Acetone
42
Marine Pollutant(Listed on Appendix B)
Is a marine pollutant if in a 10 or 1
solution or mixture?
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Marine Pollutants Appendix B to 172.101
Marine Pollutants
S.M.P.
Carbofuran
..
Carbon tetrabromide
..
Carbon tetrachloride
..
Carbophenothion
PP.....
Cartap hydrochloride
..
Chlordane
PP.....
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Shipping Papers172.200

• Each person who offers a hazardous material for
  transportation shall describe it in the
  prescribed manner.

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Basic Description172.202

• Proper shipping name (Column 2)
• Hazard class or division (Column 3)
• ID number (Column 4)
• Packing group (Column 5)
• Acetone, 3, UN1090, PG II
• Total quantity

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STRAIGHT BILL OF LADING Carrier_____________
SCAC._________ Carriers No.______
6/17/05
No. of Description of articles
Hazard I.D. Packing Weight
Class Labels packages
Class
Number Group
HM
Acetone
X
3
UN1090
II
55 gal
This is t certify that the above-named materials
are properly classified, described, packaged,
marked and labeled and are in proper condition
for transportation according to the applicable
regulations of the Department of Transportation.
Per____________________________________
____
Joe Shipper
Emergency Telephone Number_______________________
800-Cal-Help
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General Entries172.201

• Contents (hazardous and non-hazardous shipments)
• Descriptions legible and printed (manually or
  mechanically) in English
• No unauthorized codes or abbreviations
• Package description

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Contents172.201(a)(1)(i-iii)

• Hazmat and non-hazmat can go on the
• same shipping paper if
• Hazmat listed first or
• Contrasting color or
• Identified with X or RQ in hazmat column.

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STRAIGHT BILL OF LADING Carrier_____________
SCAC._________ Carriers No.______
6/17/05
No. of Description of articles
Hazard I.D. Packing Weight
Class Labels packages
Class
Number Group
HM
Acetone
3
UN1090
II
15 gal.
X
Acetic acid solution
8
UN2790
II
55 gal.
X
Paper towels
30 lbs.
This is to certify that the above-named materials
are properly classified, described, packaged,
marked and labeled and are in proper condition
for transportation according to the applicable
regulations of the Department of Transportation.
Per____________________________________
____
Joe Shipper
800-Cal-Help
Emergency Telephone Number_______________________
50
Optional Sequence172.202(b)

• UN2789, Acetic acid, glacial, 8(3), PG II

51
Hazardous Waste Manifest Information EPA form
8700-22

• Generator EPA ID and state
• Five (5) digit manifest
• generators
• Name
• Address
• Phone
• Transporter name, federal ID and state ID

• Treatment, storage and disposal facility
• Name
• Address
• EPA ID
• State ID
• Phone

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Shippers Certification172.204
Signatures

• Who
• Each person who offers
• Exceptions
• Cargo tank supplied by carrier
• Private carriage
• Return of empty tank car
• Signatures
• Legibly signed by employee/agent of shipper
• Signed manually or mechanically

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Non-bulk Package Marking and Labeling
54
Marking Non-bulk172.301

• Shipper shall MARK with
• Proper shipping name
• ID number
• Technical name (if needed)
• Consignees or consignors name and address
• Exemption (DOT-E)?

TO
ACETONE UN1090

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Large Quantities of Hazmat inNon-bulk Packages
172.301(a)(3)

• Loaded at one (1) facility
• 8,820 pounds (4,000 kg) or more
• All hazmat has same proper shipping name and ID
  number
• Transport vehicle/freight container contains no
  other materials hazmat or not
• Transport vehicle/freight container must be
• marked with ID number on both sides and
• each end

1993
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Marking Requirements172.304

• Durable and in English
• Printed or affixed
• Color to contrast with background
• Located away from other markings

ACETONE UN1090
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ORM-D Mark172.316
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Marking Hazardous Waste Containers

• Must affix WASTE MARKER on drums
• EPA ID number
• Accumulation start date
• Proper shipping name
• UN/NA ID number
• EPA waste code
• Generators name and address

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Additional non-bulk markings?

• 172.313 Poison w/SP notation
• Mark with Inhalation Hazard
• 172.322 Marine pollutant via water
• Mark with Marine Pollutant
• 172.324 Hazardous substance
• Mark with name of substance and RQ

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Marking Bulk Packages172.302

• Identification number marking
• Each side each end gt1000 gals
• Two (2) opposing sides lt 1000 gals
• How (172.332)
• Orange panel
• White square-on-point
• Materials not needing placards
• Placards

1993
1993
61
(No Transcript)
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Cargo Tank Marking
63
Tank Car Marking
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Additional Markings Bulk

• 172.313 Poisonous
• Mark Inhalation Hazard on two (2) opposing
  sides
• 172.322 Marine Pollutant
• Mark Marine Pollutant
• Two (2) sides/ends if less than 1,000 gallons
• Four (4) sides if 1,000 gallons or more
• 172.325 Elevated Temperature
• Mark HOT on two (2) opposing sides
• 172.326 Portable Tanks
• Shipping name on two (2) opposing sides
• Name of owner
• Identification number (if not visible)

65
Marking Bulk172.302

• Exemption packagings
• Mark with DOT-E number

1203
DOT-E 151
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Labeling172.400

• Shippers responsibility
• Label each non-bulk package
• Label each bulk package or portable tank unless
  placarded
• Label each overpack, freight container or unit
  load device of less than 18 cubic meters (640
  cubic feet)

67
Placement of Labels172.406

• Printed on or affixed to
• Same surface as the proper shipping name and ID
• Multiple labels within6 of each other
• Contrast with background

Acetone UN1090
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Additional Requirements172.402

• Display of class number
• Primary hazard
• First code listed inColumn 6 of HMT
• Display in lower corner
• Subsidiary hazards
• Second code(s) listed in Column 6 of HMT
• Display of class number optional (until 10/01/05)

69
Emergency Response Information 172.602

• Info needed, seven (7) items
• Presented on
• Shipping paper
• MSDS
• ERG
• Maintenance of information
• Carriers just like shipping papers
• Facility operators just like MSDS
• Telephone Number (172.604)
• On shipping paper
• Staffed while in transit

Must be included with all applicable shipments!
70
Carriage by HighwayPart 177

• Driver training
• Shipping paper review, accessibility, and
  retention
• Loading, unloading, and securement
• Segregation

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Loading Unloading 177.834Carriers and
Shippers (173.30) are both responsible

• Secure all packages
• Segregate
• No smoking
• Keep fire away
• Set brake
• Prevent relative motionbetween containers
• Vehicle attendance

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Example of Proper Securement
73
HAZARDOUS MATERIALS LOAD AND SEGREGATION CHART
Class
1.6
1.5
1.3
1.4
2
4
5
8
7
6
4
3
1.1 1.2





1.1 1.2
X
X
X
X
X
X
X
X
X
X
X
X
X
1
EXPLOSIVES





X
X
X
X
X
X
X
X
X
X
1.3
EXPLOSIVES





0
0
0
0
0
0
0
1.4
EXPLOSIVES





X
X
X
X
X
X
X
X
X
X
X
X
X
VERY INSENSITIVE EXPLOSIVES
1.5





EXTRE INSENSITIVE EXPLOSIVES
1.6
0
0
0
0
X
X
X
X
FLAMMABLE GAS
2
2.1
X
X
NONFLAMMABLE GAS
2.2
POISONOUS GAS ZONE A
0
X
X
X
X
X
X
X
X
X
X
X
2.3
0
0
0
0
0
0
0
0
0
X
X
X
POISONOUS GAS ZONE B
2.3
0
0
0
X
X
X
X
X
FLAMMABLE LIQUID
3
3
0
0
X
X
X
X
FLAMMABLE SOLID
4
4.1
0
0
X
X
X
X
X
X
SPONTANEOUSLY COMBUSTIBLE
4.2
0
0
X
X
X
X
X
DANGEROUS WHEN WET
4.3
0
0
0
X
X
X
X
X
5
5.1
OXIDIZERS
0
0
X
X
X
X
X
ORGANIC PEROXIDE
5.2
0
0
X
X
X
X
X
X
X
X
X
X
6
POISONOUS LIQUIDS PGI ZONE A
6.1
0
X
X
7
RADIOACTIVE MATERIALS
7
0
0
0
0
0
0
X
X
X
X
X
X
8
CORROSIVE LIQUIDS
8
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Placards Not Required172.500(b)

• Infectious substances
• ORM-D
• Limited quantities
• Small quantities
• Combustibles non-bulk

75
Placarding172.500

• Shipper/carrier are both responsible
• Placards must be offered to transporter by
  shipper per 172.506
• Must be maintained by transporter upon departure

76
Prohibited/PermissivePlacarding 172.502

• Material offered/transported must be hazmat
• Placard displayed represents hazard
• Conforms with requirements
• Any sign/device that could be confused for
  placard as of 10/1/01

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General Requirements172.504

• Must placard each
• Bulk load
• Freight containers goingmarine shipment
• Unit load device goingby air
• Transport vehicle withIBC/totes on board
• Railcar
• Containing any quantity!

78
Placards 1,001 Pound Exception 172.504(c)

• Transport vehicles or freight containers
• Containing less than 1,001 pounds aggregate gross
  weight of Table 2 non-bulk items
  
  
• Excepted from placarding

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(No Transcript)
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Dangerous Placard172.504(b)

• Transport vehicle, freight container, etc.,
  containing non-bulk packages of
• Two (2) or more items from Table 2 may use
  Dangerous
• Unless
• 2,205 pounds (1,000 kg) or more of one (1)
  category is loaded at one (1) location
• Effective 10/1/98
• North America only

81
Visibility and Display172.516

• Four (4) are required
• Visible from direction it faces
• Securely attached
• Clear of ladders, doors, tarps, etc.
• No dirt or water directed onto from wheels
• Displayed horizontally
• Maintained by carrier
• Contrast to background
• Holders not to obscure

82
Hazmat Incidents171.15

• Carriers, an immediate notice is
• required if
• A person is killed
• A person requires hospitalization
• Estimated damage exceeds50,000

As a result of transporting (loading, unloading
temporary storage of) hazmat/hazardous
waste. Report To 800-424-8802 (NATIONAL RESPONSE
CENTER)
83
General Hazmat Exceptions Part 173

• Small Quantities173.4
• Agriculture173.5
• Materials of Trade 173.6

84
Hazardous MaterialsCargo Tanks

• Must have manufacturers specification plate
• Must have these inspections
• External visual every year
• Internal visual every 5 years
• Leakage every year
• Pressure every 5 years
• Thickness every 2 years

85
Hazardous MaterialsCargo Tanks

• Over 1,000 gallons requires CDL endorsement
• Load has higher center of gravity more prone to
  rollover
• Surge may occur (movement of liquid within the
  tank)
• Outage may occur (expansion of product due to
  temperature change)

86
Hazardous MaterialShipping Procedure

• Identify/classify material
• Select/verify packaging
• Communicate hazard
• Shipping papers
• Markings
• Labels
• Placards
• Properly load
• Safely transport

87
THANK YOU !
John Backowski 602-850-6002 jbackowski_at_aztrucking.
com