Mono(dinitrogen) and Carbon Monoxide Adducts of Bis(cyclopentadienyl) Titanium Sandwiches

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Mono(dinitrogen) and Carbon Monoxide Adducts of
Bis(cyclopentadienyl) Titanium Sandwiches

• Tamara E. Hanna, Emil Lobkovsky, and Paul J.
  Chirik
• J. Am. Chem. Soc. 2006, 128, 6018 - 6019

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R SiMe2But
J. Am. Chem. Soc. 1998, 120, 10264
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J. Am. Chem. Soc. 2004, 126, 14688.
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Nature 2004, 427, 527.
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1 R SiMe3 2 R SiMe2Ph 3 R CHMe2
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1 R SiMe3 2 R SiMe2Ph 3 R CHMe2
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1 R SiMe3 2 R SiMe2Ph 3 R CHMe2
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J. Am. Chem. Soc. 2004, 126, 14688.
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J. Am. Chem. Soc. 2000, 122, 6476.
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1 R SiMe3 2 R SiMe2Ph 3 R CHMe2
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Ti(1) C(10) 1.9786(19) Å
C(10) O(1) 1.151(2) Å
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s-donating, weakly p-acidic
N2
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