????????????? Ph.D. Program of Department of Chemistry ????????? 1st Semester of 2006 Academic Year

1
????????????? Ph.D. Program of Department of
Chemistry????????? 1st Semester of 2006 Academic
Year
????????(?)Special Topic on Advanced Physical
Chemistry Advanced Photochemistry

• ????Lecture?????, Prof. Tai-Shan Fang,
• e-mail
  chetsf_at_scc.ntnu.edu.tw
• http//icho.chem.ntnu.edu.tw/fang/index.htm
  
• ????Class LocationC304??
• ???????,??200--500

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(No Transcript)
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95 1??2698(CMD0021 )?? ????????(?), ??
???(? 7-9 C304,), ? 7??? (Updated Oct. 12, 2006)
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95 1??2698(CMD0021 )?? ????????(?), (?)??
???(? 7-9 C304,), ? 7??? (Updated Oct. 12, 2006)
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????????? Lecture Contents and
References????????????,??????????????,???????????
?????????,??????????

• (1) Modern Molecular Photochemistry of Organic
  Molecules
• by Nicholas J. Turro, V. Ramamurthy,
  and Juan Scaiano,
• Forthcoming in 2007! (University
  Science book)
• Chapt. 13 and 14.(Contrained Medium
  Effect and Oxygen in
• Photochemistry) , review basic organic
  photochemistry
• (2) Chemical Kinetics and Reaction Dynamics by
  Paul L.
• Houston, McGraw-Hill Higher Education ,
  Chapter 7.
• Photochemistry (exercise)
• (3) Modern Physical Organic Chemistry by Eric V.
  Anslyn and
• Dennis A. Dougherty, 2005 (University
  Science book),
• Chapter 17. Electronic Organic
  Materials, Solutions
• (exercise)
• (4) Recent Literatures and Journals

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??????????

• 1."???????????????????????????????2006???????????(
  ???   http//www.sinica.edu.tw/chem/TBIC/TBIC.htm)
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  ??????????Green Bay Howard Hotel (???????)
  Speakers Program posterRegistration
  Transportation Origin  
• 2. ??????????????-The 1st International
  Conference of Cutting-Edge Organic Chemistry in
  Asia (ICCEOCA-1)??10?16?10?20????????ICCEOCA-1????
  ?10?21??10?24????????????? Abstract Submission
  (Abstract Deadline September 15, 2006)
  Registration1"??????????????????
• 3.??????95 ?11/25-26 ???????
• 4.12?10 15? ???????????????????????
• 5.Dec.14-16?????22??????????

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95????????(?)by ???Advanced Photochemistry
??(??)(?)???, 1400-1700 C304

• Syllabus
• Modern Molecular Photochemistry of Organic
  Molecules
• Nicholas J. TurroColumbia UniversityV.
  RamamurthyTulane UniversityJuan
  ScaianoUniversity of Ottawa
• The course will involve a discussion of modern
  molecular organic photochemistry with emphasis on
  mechanisms. Useful texts and references

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Forthcoming in 2007!Old Ed. 1992, OK!!

• With two new co-authors, V. Ramamurthy and J.C.
  Scaiano, Nick Turro has completely revised and
  updated the 1992-edition of his benchmark text,
  Modern Molecular Photochemistry.  The text will
  present, at a level understandable by seniors and
  first year graduate students, the first totally
  integrated theory of organic photochemistry,
  including the first visualization of the role of
  electron spin at all levels.  In addition,
  chapters describing how experiment and theory can
  be applied to an understanding of the fundamental
  chromophors of organic chemistry will be
  presented.
• If you would like to receive an e-mail
  announcement when this book is published, click
  here to send a . Please be sure to mention the
  title of the forthcoming book or books you would
  like to receive publication notification of.

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Contents

• 1. Introduction and Overview2. Electronic,
  nuclear and spin state of electronically excited
• states3. Transitions between states4.
  Radiative transitions between states5.
  Radiationless transitions between states6.
  Theoretical organic photochemistry7. Energy and
  electron transfer processes8. Mechanistic
  organic photochemistry9. Photochemistry of
  carbonyl compounds10. Photochemistry of
  olefins11. Photochemistry of enones12.
  Photochemistry of aromatics13. Medium effects on
  photochemical processes organized
• and constraining media14. Oxygen in
  photochemistryIndex

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Chapter 7 Photochemistry

• Paul L. Houston, Chemical Kinetics and
  Reaction Dynamics 1st Ed. (2001) , McGraw-Hill
  Higher Education
• This textbook, designed for upper level
  undergraduates and beginning graduate students,
  was published by WCB/McGraw-Hill but is no longer
  available in printed form. A few copies are left
  at the publisher, which will run off a separate
  printing if there is demand, and a few copies are
  left at Amazon. A separate book containing the
  problems and solutions to this text is also
  available. As soon as the rights to the text are
  transferred back to the author from McGraw-Hill,
  the text will be made available by another
  publisher. I am pleased that Dover has agreed to
  publish it. With luck, we may have copies
  available for the Fall semester of 2006 at a
  price students may be better able to afford
• To obtain a copy of this book for review please
  visit theAmazon.com
• For a (favorable) review, see Krenos, John R. J.
  Chem. Educ. 2001 78 1466
• Errata

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Customer Reviews Average Customer Review by
Yummy, December 16, 2005

• Chemical kinetics and reaction dynamics are not
  easy subjects, demanding quite a lot of physics
  in some complicated settings. Thus, it is all the
  more impressive that Paul Houston has managed to
  write this extraordinarily clear and concise text
  that is accessible to an advanced undergraduate.
  Do not get me wrong the prerequisites for this
  book are extensive. A good grasp of basic
  newtonian mechanics, quantum mechanics,
  spectroscopy, and statistical thermodynamics are
  musts. But nothing is needed beyond what can be
  expected from a good, stiff one-year course in
  physical chemistry. From the first chapter on
  the kinetic theory of gases, Houston's focus on
  the physics - on keeping derivations short and
  clear, on connecting formulae with sound physical
  intuition - is striking. It does not lag as the
  book goes on. Houston continues with a clean
  exposition of empirical chemical kinetics and how
  to integrate and/or simplify the resulting
  differential equations. The grungy business of
  theoretical kinetics - how to kludge your way to
  a theoretical gas-phase reaction rate constant -
  is well treated after that. In the third chapter,
  Houston delivers an elegant and unified
  flux-driven treatment of transport phenomena. He
  gets the basic equations correct up to a
  numerical factor with a minimum of effort. This
  is beautiful I wish chemical engineers would
  read this before beginning their own transport
  travails! There are then several chapters on the
  chemistry of more complicated systems, like
  solution-phase, solid surface-phase, and
  photochemical reactions. While I haven't read
  these, I am sure they are wonderful. The high
  point, in my opinion, is the final chapter on
  reaction dynamics. Its ongoing tacit motivation
  is the question, "How does a hydrogen fluoride
  laser work?" Read, and you will learn. In doing
  so, you will also become acquainted with the
  basic concepts in gas-phase reaction dynamics
  the details of the crossed-beam molecular
  scattering experiment, the concept of a potential
  energy surface, and what these can tell us about
  reaction mechanisms. Throughout Houston, the
  emphasis on looking up from the math and seeing
  the physical big picture prevents the blind and
  frustrating equation-crunching which is all too
  common in the quantitative sciences. This
  little book is really amazing. It takes you from
  a good undergraduate background to the forefront
  of modern chemical physics research with minimal
  pain and maximal excitement. Read it.

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Modern Physical Organic Chemistry

• Eric V. AnslynThe University of Texas, Austin
  

• Dennis A. DoughertyCalifornia Institute of
  Technology

Chapter 17 Electronic Organic Materials,
Solutions
14

• Dennis A. Dougherty, below, received a PhD from
  Princeton with Kurt Mislow, followed by a year of
  postdoctoral study with Jerome Berson at Yale. In
  1979 he joined the faculty at the California
  Institute of Te chnology, where he is now George
  Grant Hoag Professor of  Chemistry. Dougherty's
  extensive research interests have taken him to
  many fronts, but he is perhaps best known for
  development of the cation-p interaction, a novel
  but potent noncovalent binding interaction. More
  recently, he has addressed molecular
  neurobiology, developing the in vivo nonsense
  suppression method for unnatural amino acid
  incorporation into proteins expressed in living
  cells. This powerful new tool enables physical
  organic chemistry on the brain - chemical-scale
  studies of the molecules of memory, thought, and
  sensory perception and the targets of treatments
  for Alzheimer's disease, Parkinson's disease,
  schizophrenia, learning and attention deficits,
  and drug addiction.  His group is now working on
  extensive experimental and computational studies
  of the bacterial mechanosensitive channels MscL
  and MscS, building off the crystal structures of
  these channels recently reported by the Rees
  group at Caltech.

Eric V. Anslyn, right, received his PhD in
Chemistry from the California Institute of
Technology under the direction of Robert Grubbs.
After completing post-doctoral work with Ronald
Breslow at Columbia University, he joined the
faculty at the University of Texas at Austin,
where he became a Full Professor in 1999.  He
currently holds four patents and is the recipient
of numerous awards and honors, including the
Presidential Young Investigator, the Alfred P.
Sloan Research Fellow, the Searle Scholar, the
Dreyfus Teacher-Scholar Award, and the Jean
Holloway Award for Excellence in Teaching.  He is
also the Associate Editor for the Journal of the
American Chemical Society and serves on the
editorial boards of Supramolecular Chemistry and
the Journal of Supramolecular Chemistry.  His
primary research is in physical organic chemistry
and bioorganic chemistry, with specific interests
in catalysts for phosphoryl and glycosyl
transfers, receptors for carbohydrates and
enolates, single and multi-analyte sensors the
development of an electronic tongue, and
synthesis of polymeric molecules that exhibit
unique abiotic secondary structure. 
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CONTENTS

• Chapter 1 Introduction to Structure and Models
  of Bonding, Solutions
• Chapter 2 Strain and Stability, Solutions
• Chapter 3 The Thermodynamics of Solutions and
  Noncovalent Binding Forces, Solutions
• Chapter 4 Molecular Recognition and
  Supramolecular Chemistry, Solutions
• Chapter 5 Acid-Base Chemistry, Solutions
• Chapter 6 Stereochemistry, Solutions
• Chapter 7 Energy Surfaces and Kinetic Analyses,
  Solutions
• Chapter 8 Experiments Related to Thermodynamics
  and Kinetics, Solutions
• Chapter 9 Catalysis, Solutions
• Chapter 10 Organic Reaction Mechanisms Part 1
  Reactions Involving Additions and/or
  Eliminations, Solutions
• Chapter 11 Organic Reaction Mechanisms Part II
  Substitutions at Aliphatic Centers and Thermal
  Isomerizations/Rearrangements, Solutions
• Chapter 12 Organotransition Metal Reaction
  Mechanisms and Catalysis, Solutions
• Chapter 13. Organic Materials Chemistry,
  Solutions
• Chapter 14. Advanced Concepts in Electronic
  Structure Theory, Solutions  Chapter 15
  Thermal Pericyclic Reactions, Solutions
• Chapter 16 Photochemistry, Solutions
• Chapter 17 Electronic Organic Materials,
  Solutions
• Appendix

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"A REMARKABLE ACHIEVEMENT"

• "Spectacular! Congratulations! I plan to
  recommend it to all of my research group members
  and to those students in my class who are getting
  hooked on organic chemistry.  This is going to be
  a winner."--Peter Vollhardt, University of
  California at Berkeley"Anslyn and Dougherty
  have done an admirable and scholarly job to put
  the essence of this important subject between the
  covers of a single text.  I can enthusiastically
  recommend the text for anyone who is teaching a
  course dealing with the essentials of physical
  organic chemistry and more."--Nicholas J. Turro,
  Columbia University
• The text will certainly inspire those coming to
  physical organic chemistry as a first love, as
  well as those coming from a bordering discipline
  who wish to acquire the insight that physical
  organic chemistry can provide.--Barry
  Carpenter, Cornell University
• This much needed text places physical organic
  chemistry in its most modern context as the
  foundation of not only organic chemistry, but as
  the basis for understanding the most current
  research in supramolecular chemistry, organic
  materials science, catalysis, and
  organometallics.  This book is the new
  authoritative physical organic resource that will
  benefit researchers, students, and teachers
  alike.--Timothy M. Swager, Massachusetts
  Institute of Technology
• "By building the text from the ground up, the
  authors have managed to incorporate modern
  applications of the theories of physical organic
  chemistry throughout, in a way that no revision
  of an existing text can hope to
  accomplish."Thomas Poon, Claremont Colleges
• "This is a high quality book that fills a real
  need in our field, and that makes every other
  book in this area immediately obsolete.
  Congratulations to the authors on a remarkable
  achievement!"David I. Schuster, New York
  University This is the first modern textbook,
  written in the 21st century, to make explicit the
  many connections between physical organic
  chemistry and critical fields such as
  organometallic chemistry, materials chemistry,
  bioorganic chemistry, and biochemistry. In the
  latter part of the 20th century, the field of
  physical organic chemistry went through dramatic
  changes, with an increased emphasis on
  noncovalent interactions and their roles in
  molecular recognition, supramolecular chemistry,
  and biology the development of new materials
  with novel structural features and the use of
  computational methods. Contemporary chemists
  must be just as familiar with these newer fields
  as with the more established classical topics.
• This completely new landmark text is intended to
  bridge that gap. In addition to covering
  thoroughly the core areas of physical organic
  chemistry structure and mechanism the book
  will escort the practitioner of organic chemistry
  into a field that has been thoroughly updated . 
  The foundations and applicabilities of modern
  computational methods are also developed.
• Written by two distinguished researchers in this
  field, Modern Physical Organic Chemistry can
  serve as a text for a year-long course targeted
  to advanced undergraduates or first-year graduate
  students, as well as for a variety of shorter
  courses on selected aspects of the field. It
  will also serve as a landmark new reference text,
  and as an introduction to many of the more
  advanced topics of interest to modern
  researchers.  An accompanying Student Solutions
  Manual will become available.

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Student Solutions Manualto accompany Modern
Physical Organic Chemistry

• The Author sMichael B. Sponsler earned his PhD
  from the California Institute of Technology in
  1987, working as an NSF Graduate Fellow with
  Dennis A. Dougherty. He did research as an NIH
  Post-doctoral Fellow with Robert G. Bergman at
  the University of California, Berkeley and then
  accepted a faculty position at Syracuse
  University in 1989, where he is now Associate
  Professor. His research involves physical
  organic studies in the diverse areas of
  conjugated organometallic complexes and liquid
  crystalline holographic recording materials. The
  organometallic studies include synthesis and
  characterization of both mixed-valence complexes
  with polyenediyl bridges and related polymers.
  Applications in molecular electronics and
  nanotechnology are under investigation. The
  holographic studies are focused on new strategies
  for producing electrically switchable holograms.
• Bios for Eric V. Anslyn and Dennis A. Dougherty
  can be found by linking to the page for their
  textbook,  Modern Physical Organic Chemistry

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Photochemistry Invited Lecturers Yuan-Pern
Lee (chairperson), National Chiao-Tung
University Chi-Kung Ni, Institute of Atomic and
Molecular Sciences, Academia Sinica , Arthur G.
Suits, Wayne State University Mitchio Okumura
(chairperson), California Institute of
Technology, Robert E. Continetti, University of
California, San Diego Cheuk-Yiu Ng, University
of California, Davis
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??????? Exams and Evaluation

• (1)Advanced Photochem Exam  50 (closed book 2
  hours exam, Nov.15)
• (2)Term Paper  25(Reviews on the subject in your
  research field)
• (3)Seminar Presentation 25 (your research and
  proposal for future)