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8. factors affecting acid/base strength

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A electronegativity; the more electronegative A is, the greater the acid strength of HA ... 8. factors affecting acid/base strength ... – PowerPoint PPT presentation

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Title: 8. factors affecting acid/base strength


1
  • 8. factors affecting acid/base strength
  • binary acids
  • of the same group
  • AH bond strength the stronger the bond the
    weaker the acid
  • of the same row
  • A electronegativity the more electronegative A
    is, the greater the acid strength of HA

2
  • 8. factors affecting acid/base strength
  • oxoacids HnYOm the acidic hydrogens are bound
    to the oxygen atoms which are in turn bound to Y
  • examples, with Lewis structures HNO3, H2SO4,
    HClO3
  • oxoacids with equal numbers of O and OH groups
    acid strength increases with electronegativity of
    Y
  • HClOgtHBrOgtHIO
  • oxoacids with same Y but different numbers of O
    atoms acid strength increases with number of O
    atoms
  • H2SO4gtH2SO3
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