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Nonrenewable Energy Resources

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Title: Nonrenewable Energy Resources


1
Chapter 12 Nonrenewable Energy Resources
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Nonrenewable Energy
  • Nonrenewable energy resources- fossil fuels
    (coal, oil, natural gas) and nuclear fuels.

3
Energy Sources
  • Modern society requires large quantities of
    energy that are generated from the earths
    natural resources.
  • Primary Energy Resources The fossil fuels(oil,
    gas, and coal), nuclear energy, falling water,
    geothermal, and solar energy.
  • Secondary Energy Resources Those sources which
    are derived from primary resources such as
    electricity, fuels from coal, (synthetic natural
    gas and synthetic gasoline), as well as alcohol
    fuels.

www.lander.edu/rlayland/Chem20103/chap_12.ppt
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Thermodynamics
  • The laws of thermodynamics tell us two things
    about converting heat energy from steam to work
  • 1) The conversion of heat to work cannot be 100
    efficient because a portion of the heat is
    wasted.
  • 2) The efficiency of converting heat to work
    increases as the heat temperature increases.

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Energy Units and Use
  • Btu (British thermal unit) - amount of energy
    required to raise the temperature of 1 lb of
    water by 1 ºF.
  • cal (calorie) - the amount of energy required to
    raise the temperature of 1 g of water by 1 ºC.
    Commonly, kilocalorie (kcal) is used.
  • 1 Btu 252 cal 0.252 kcal
  • 1 Btu 1055 J (joule) 1.055 kJ
  • 1 cal 4.184 J

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Energy Units and Use
  • Two other units that are often seen are the
    horsepower and the watt. These are not units of
    energy, but are units of power.
  • 1 watt (W) 3.412 Btu / hour
  • 1 horsepower (hp) 746 W
  • Watt-hour - Another unit of energy used only to
    describe electrical energy. Usually we use
    kilowatt-hour (kW-h) since it is larger.
  • quad (Q) - used for describing very large
    quantities of energy. 1 Q 1015 Btu

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Energy Use
  • Commercial energy sources- those that are bought
    and sold, such as coal, oil and natural gas.
  • Subsistence energy sources- those gathered by
    individuals for their own use such as wood,
    charcoal and animal waste.

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Changes in U.S. Energy Use
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Energy resources removed from the earths crust
include oil, natural gas, coal, and uranium
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Process of Energy Use
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Overall Fuel Efficiency of U.S. Automobiles
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Electricity Generation
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Electricity Generation
  • The burning fuel from coal transfers energy to
    water, which becomes steam.
  • The kinetic energy contained within the steam is
    transferred to the blades of a turbine, a large
    device that resembles a fan.
  • As the energy in the steam turns the turbine, the
    shaft in the center of the turbine turns the
    generator.
  • This mechanical motion generates energy.

14
Energy Efficiency
  • Most coal burning power plants are about 35
    efficient.

15
Cogeneration
  • Cogeneration- using a fuel to generate
    electricity and to produce heat.
  • Example- If steam is used for industrial purposes
    or to heat buildings it is diverted to turn a
    turbine first.
  • This improves the efficiency to as high as 90.

16
Coal
  • Coal- a solid fuel formed primarily from the
    remains of trees, ferns, and other plant
    materials that were preserved 280-360 million
    years ago.
  • Four types of coal ranked from lesser to greater
    age, exposure to pressure, and energy content.
  • These four types are lignite, sub-bituminous,
    bituminous, and anthracite.
  • The largest coal reserves are in the United
    States, Russia, China, and India.

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Coal
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Ranks of Coal
  • Lignite A brownish-black coal of low quality
    (i.e., low heat content per unit) with high
    inherent moisture and volatile matter. Energy
    content is lower 4000 BTU/lb.
  • Subbituminous Black lignite, is dull black and
    generally contains 20 to 30 percent moisture
    Energy content is 8,300 BTU/lb.
  • Bituminous most common coal is dense and black
    (often with well-defined bands of bright and dull
    material). Its moisture content usually is less
    than 20 percent. Energy content about 10,500 Btu
    / lb.
  • Anthracite A hard, black lustrous coal, often
    referred to as hard coal, containing a high
    percentage of fixed carbon and a low percentage
    of volatile matter. Energy content of about
    14,000 Btu/lb.

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Main Coal Deposits
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Advantages and Disadvantages of Coal
Advantages Disadvantages
Energy-dense Contains impurities
Plentiful (300 years of use remaining) Release impurities into air when burned
Easy to exploit by surface mining Trace metals like mercury, lead, and arsenic are found in coal
Technological demands are small Combustion leads to increased levels of sulfur dioxide and other air pollutants into the atmosphere.
Economic costs are low Ash is left behind
Easy to handle and transport Carbon is released into the atmosphere which contributes to climate change
Needs little refining Major threat to health
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Acid Mine Drainage
  • The impact of mine drainage on a lake after
    receiving effluent from an abandoned tailings
    impoundment for over 50 years

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Relatively fresh tailings in an impoundment.
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Petroleum
  • Petroleum- a mixture of hydrocarbons, water, and
    sulfur that occurs in underground deposits.
  • Oil and gasoline make this ideal for mobile
    combustion, such as vehicles.
  • Formed from the remains of ocean-dwelling
    phytoplankton that died 50-150 million years ago.
  • Countries with the most petroleum are Saudi
    Arabia, Russia, the United States, Iran, China,
    Canada, and Mexico.

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Petroleum
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Oil in U.S.
  • 2.3 of world reserves
  • uses nearly 30 of world reserves
  • 65 for transportation
  • increasing dependence on imports.

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Advantages and Disadvantages of Petroleum
Advantages Disadvantages
Convenient to transport and use Releases carbon dioxide into atmosphere
Relatively energy-dense Possibility of leaks when extracted and transported
Cleaner-burning than coal Some water pollution
Low Cost with subsidies Ample supply for about 50 years Releases sulfur, mercury, lead, and arsenic into the atmosphere when burned When price is low discourages alternate choices encourages waste
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Natural Gas
  • Natural gas- exists as a component of petroleum
    in the ground as well as in gaseous deposits
    separate from petroleum.
  • Contains 80 to 95 percent methane and 5 to 20
    percent ethane, propane, and butane.

43
Sources of Natural Gas
  • Russia Kazakhstan - almost 40 of world's
    supply.
  • Iran (15), Qatar (5), Saudi Arabia (4),
    Algeria (4), United States (3), Nigeria (3),
    Venezuela (3)
  • 9095 of natural gas in U.S. domestic (411,000
    km 255,000 miles of pipeline).

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billion cubic metres
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Advantages and Disadvantages Natural Gas
Advantages Disadvantages
Contains fewer impurities and therefore emits almost no sulfur dioxide or particulates When unburned, methane escapes into the atmosphere
Emits only 60 as much carbon dioxide as coal Ample supplies up to 150 years Low cost with huge subsidies Exploration of natural gas has the potential of contaminating groundwater Shipped across oceans as highly flammable LNG
46
Other Fossil Fuels
  • Oil sands- slow-flowing, viscous deposits of
    bitumen mixed with sand, water, and clay.
  • Bitumen (tar or pitch)- a degraded type of
    petroleum that forms when a petroleum migrates
    close to the surface, where bacteria metabolize
    some of the light hydrocarbons and others
    evaporate.

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The Hubbert Curve
  • Hubbert curve- a graph that shows the point at
    which world oil production would reach a maximum
    and the point at which we would run out of oil.

49
The Future of Fossil Fuel Use
  • If current global use continues, we will run out
    of conventional oil in less than 40 years.
  • Coal supplies will last for at least 200 years,
    and probably much longer.

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  • Burning any fossil fuel releases carbon dioxide
    into the atmosphere and thus promotes global
    warming.
  • Comparison of CO2 emitted by fossil fuels and
    nuclear power.

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Nuclear Energy
  • Fission- a nuclear reaction in which a neutron
    strikes a relatively large atomic nucleus, which
    then splits into two or more parts.

52
Nuclear Reactors
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Nuclear Reactors
  • Fuel rods- the cylindrical tubes that house the
    nuclear fuel used in a nuclear power plant.
  • Nuclear power plants work by using heat from
    nuclear fission to heat water. This water
    produces the steam to turn the turbine, which
    turns a generator.
  • Control rods- cylindrical devices that can be
    inserted between the fuel rods to absorb excess
    neutrons, thus slowing or stopping the fission
    reaction.

54
Advantages and Disadvantages of Nuclear Energy
Advantages Disadvantages
No air pollution is produced Possibility of accidents
Countries can limit their need for imported oil Emits 1/6 as much pollution as coal Low environmental impact if no accidents Disposal of the radioactive waste High cost even with high subsidies Spreads knowledge for nuclear weapons Low net energy yield
55
Radioactive Waste
  • Radioactive waste- once the nuclear fuel can not
    produce enough heat to be used in a power plant
    but it continues to emit radioactivity.
  • This waste must be stored in special, highly
    secure locations because of the danger to living
    organisms.

56
Radioactive Waste
  • High-level radioactive waste- the form used in
    fuel rods.
  • Low-level radioactive waste- the protective
    clothing, tools, rags, and other items used in
    routine plant maintenance.

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Chernobyl
  • April 26, 1986, reactor explosion (Ukraine) flung
    radioactive debris into atmosphere
  • Health ministry reported 3,576 deaths
  • Green Peace estimates32,000 deaths
  • About 400,000 people were forced to leave their
    homes
  • 160,000 sq km (62,00 sq mi) contaminated
  • gt Half million people exposed to dangerous levels
    of radioactivity
  • Cost of incident gt 358 billion

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Three Mile Island
  • March 29, 1979, a reactor near Harrisburg, PA
    lost coolant water because of mechanical and
    human errors and suffered a partial meltdown
  • 50,000 people evacuated another 50,000 fled
    area
  • Unknown amounts of radioactive materials released
  • Partial cleanup damages cost 1.2 billion
  • Released radiation increased cancer rates.

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Fusion
  • Nuclear fusion- the reaction that powers the Sun
    and other stars. This occurs when lighter nuclei
    are forced together to produce heavier nuclei and
    heat is released.
  • Fusion is a promising, unlimited source of energy
    in the future, but so far scientists have had
    difficulty cotaining the heat that is produced.
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