Why should Allah chastise you if you are grateful and believe And Allah is the Multiplier of rewards

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Why should Allah chastise you if you are grateful
and believe? And Allah is the Multiplier of
rewards, Knowing
An Nisaa 4147
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But Allah was not going to chastise them while
you were among them, nor is Allah going to
chastise them while yet they ask for forgiveness.
Al Anfal 8 33.
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Say My Lord would not care for you were it not
for your prayer, but you have indeed rejected
(the truth), so that which shall cleave shall
come. Al Furqaan 25 77

• Allah turns in mercy to those who pray to Him or
  call on Him. So the excellence of a man depends
  on the degree of sincerity and devotedness in his
  supplication unto Allah.

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And when My servants ask you concerning Me, then
surely I am very near I answer the prayer of the
suppliant when he calls on Me, so they should
answer My call and believe in Me that they may
walk in the right way. Al Baqarah 2 186
this verse short as it is - repeats the first
person singular pronoun seven times it is the
only verse with this characteristic in the whole
of Quran.
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And certainly We created man, and We know what
his mind suggests to him, and We are nearer to
him than his life-vein. Qaaf 50 16

• Allah created man, so by virtue of His being the
  creator, He is aware of man's inherent
  weaknesses. He gave man intellect, consciousness
  and free-will. The phrase "nearer than the
  jugular vein" implies that Allah knows, more
  truly, the innermost state of man's feelings and
  consciousness, than does his own self.

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And your Lord says "Call on Me I will answer
your (Prayer) but those who are too arrogant to
serve Me will surely find themselves in Hell - in
humiliation! Al Ghaafir 40 60
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Imam Ali ibna abi Talib says

• Put faith in Allah. Seek His protection.
• Direct your prayers, requests, solicitations and
  supplications to Him and Him alone.
• To give as well as to withhold lies in His (only
  in His) power.
• Ask as much of His favours as you can.
• Know that Allah owns the treasures of the heavens
  and the earth. Not only He has given permission
  to ask for His mercy and favours, but also has
  promised to listen to your prayers. He has not
  appointed guards to prevent your prayers reaching
  Him. Invoke His help in difficulties and
  distress. Implore Him to grant you long life and
  sound health. Pray to Him for prosperity.
• Think over it that by simply granting you the
  privilege of praying for His favours and mercy,
  He has handed over the keys of His treasures to
  you. Whenever you are in need, pray, and He gives
  His favours and blessings.
• Sometimes you find requests are not immediately
  granted. Do not be disappointed. Fulfillment of
  desires rests with the true purpose or intention
  of the prayer. More often fulfillment is delayed
  because the merciful Lord wants to bestow upon
  you suitable rewards. In the meantime bear
  patiently hardships, believing sincerely in His
  help. You will get better favours, because,
  unknowingly, you may ask for things which are
  really harmful to you. Many of your requests, if
  granted, may bring eternal damnation.
• 8. So, at times, withholding fulfillment is a
  blessing in disguise.